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The Origin of Siloxanes

Jun 20, 2023

The Si-H addition of hydrogen containing polymethylsiloxane (PHMS) and acrylate monomers mainly occurs in the bulk homogeneous solution, and is less used in lotion. Water was selected as the dispersion medium, and hydrogen containing polymethyl siloxane, Butyl acrylate, and Methacrylamide were used as raw materials to conduct lotion polymerization at 80 ° C. PHMS/Butyl acrylate (BA)/light Methacrylamide (NMA) organosilicon composite lotion with both excellent properties was obtained. The morphology, particle size, and film properties of its latex particles were studied. The results showed that the concentration of initiator increased, The particle size of lotion first decreases and then rapidly increases, while the conversion rate first increases and then decreases.

Under the action of chlorolead acid, dimethyl diphenyl siloxane, vinyl Trimethoxysilane and Glycidol acrylate blocked by dimethyl hydrogen are selected for hydrosilylation Addition reaction to obtain a siloxane. The coating is polymerized with styrene methacrylate butyl acrylate methacrylic acid mixed lotion, and dibutyltin Lauric acid curing agent is added. After coating, the coating has good appearance and acid resistance.

Under the catalytic action of isopropanol solution of chlorolead acid, hydrogen containing silicone oil was hydrogenated with triethylene glycol acrylate (TPGDA) in toluene or xylene solvent, and photosensitive silicone acrylate was obtained by reacting at 90~12o · c for 4 hours. The UV curing performance and degree of complete reaction of the product were studied. The results showed that it took 5 minutes for the reaction product of hydrogen terminated silicone oil to fully cure, The organic silicone acrylate obtained from the reaction of side hydrogenated silicone oil has a light curing time of only 1 minute; In addition, due to the Electronic effect and volume effect, the Si-H bond at the end of polysiloxane is more active than the Si-H bond in the molecular chain, and the hydrosilylation reaction is more complete.

SILIBASE is the combination of "SILICONE" and "BASED", which means that SILIBASE SILICONE is focused on producing and selling all kinds of SILICONE-BASED new materials.Our main products are Acrylic Modified Silicone Resin Emulsion,Epoxy Modified Silicone Resin Emulsion,Smokeless Silicone Resin,Self-drying Silicone Resin,Highly Active Silicone Resin,Methyl Silicone Resin Intermediate.

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